Chile
Formed: 1895 Manager: Marcelo Bielsa [ARG]
| Number | Name | Nat | Pos | Height | Weight | Date of Birth | Birth Place | Current Club |
| 1 | Claudio Bravo | CHI | G | 1.84 | 84 | 13-04-83 | Viluco | Real Sociedad |
| 2 | Ismael Fuentes | CHI | D | 1.81 | 79 | 04-08-81 | Petroca | Jaguares de Chiapas |
| 3 | Waldo Ponce | CHI | D | 1.80 | 69 | 04-12-82 | Los Andes | O'Higgins |
| 4 | Mauricio Isla | CHI | D | 1.76 | 75 | 12-06-88 | Buin | Udinese |
| 5 | Pablo Contreras | CHI | D | 1.81 | 74 | 11-09-78 | Santiago | PAOK |
| 6 | Carlos Carmona | CHI | M | 1.79 | 77 | 21-02-87 | Coquimbo | Reggina |
| 7 | Alexis Sánchez | CHI | F | 1.68 | 62 | 19-12-88 | Tocopilla | Udinese |
| 8 | Arturo Vidal | CHI | D | 1.81 | 74 | 22-05-87 | Santiago | Bayer Leverkusen |
| 9 | Humberto Suazo | CHI | F | 1.72 | 79 | 10-05-81 | San Antonio | Monterrey |
| 10 | Jorge Valdivia | CHI | M | 1.73 | 71 | 19-10-83 | Maracaibo | Al-Ain |
| 11 | Mark González | CHI | M | 1.75 | 70 | 10-07-84 | Durban | CSKA Moscow |
| 12 | Miguel Pinto | CHI | G | 1.80 | 73 | 04-07-83 | Santiago | Universidad de Chile |
| 13 | Marco Estrada | CHI | M | 1.75 | 81 | 28-05-83 | Viña del Mar | Universidad de Chile |
| 14 | Matías Fernández | CHI | M | 1.77 | 75 | 15-05-86 | Merlo | Sporting CP |
| 15 | Jean Beausejour | CHI | M | 1.79 | 80 | 01-06-84 | Santiago | América |
| 16 | Fabián Orellana | CHI | F | 1.69 | 68 | 27-01-86 | Santiago | Udinese |
| 17 | Gary Medel | CHI | M | 1.72 | 71 | 03-08-87 | Santiago | Universidad Católica |
| 18 | Gonzalo Jara | CHI | D | 1.78 | 77 | 29-08-85 | Santiago | WBA |
| 19 | Gonzalo Fierro | CHI | F | 1.71 | 70 | 21-03-83 | Santiago | Flamengo |
| 20 | Rodrigo Millar | CHI | M | 1.83 | 75 | 03-11-81 | Arauco | Colo-Colo |
| 21 | Rodrigo Tello | CHI | M | 1.67 | 70 | 14-10-79 | Santiago | Beşiktaş |
| 22 | Esteban Paredes | CHI | F | 1.76 | 78 | 01-08-80 | Santiago | Colo-Colo |
| 23 | Luis Marín | CHI | G | 1.88 | 87 | 18-05-83 | Valparaíso | Unión Española |