Chile
Formed: 1895 Manager: Jorge Sampaoli [ARG]
| Number | Name | Nat | Pos | Height | Weight | Date of Birth | Birth Place | Current Club |
| 1 | Claudio Bravo | CHI | G | 1.84 | 84 | 13-04-83 | Viluco | Barcelona |
| 2 | Eugenio Mena | CHI | D | 1.71 | 73 | 18-07-88 | Viña del Mar | Cruzeiro |
| 3 | Miiko Albornoz | CHI | D | 1.80 | 80 | 30-11-90 | Stockholm | Hannover 96 |
| 4 | Mauricio Isla | CHI | D | 1.76 | 72 | 12-06-88 | Buin | QPR (On Loan) |
| 5 | Francisco Silva | CHI | M | 1.78 | 75 | 11-02-86 | Santiago | Club Brugge (On Loan) |
| 6 | José Pedro Fuenzalida | CHI | M | 1.70 | 67 | 22-02-85 | Santiago | Boca Juniors |
| 7 | Alexis Sánchez | CHI | F | 1.68 | 62 | 19-12-88 | Tocopilla | Arsenal |
| 8 | Arturo Vidal | CHI | M | 1.81 | 74 | 22-05-87 | Santiago | Juventus |
| 9 | Mauricio Pinilla | CHI | F | 1.85 | 75 | 04-02-84 | San Bernardo | Atalanta (On Loan) |
| 10 | Jorge Valdivia | CHI | M | 1.73 | 71 | 19-10-83 | Maracaibo | Palmeiras |
| 11 | Eduardo Vargas | CHI | F | 1.73 | 74 | 20-11-89 | Santiago | QPR (On Loan) |
| 12 | Paulo Garcés | CHI | G | 1.82 | 77 | 02-08-84 | Parral | Colo-Colo |
| 13 | José Rojas | CHI | D | 1.74 | 75 | 23-06-83 | Talagante | Universidad de Chile |
| 14 | Matías Fernández | CHI | M | 1.77 | 75 | 15-05-86 | Merlo | Fiorentina |
| 15 | Jean Beausejour | CHI | M | 1.79 | 80 | 01-06-84 | Santiago | Colo-Colo |
| 16 | David Pizarro | CHI | M | 1.70 | 65 | 11-09-79 | Valparaiso | Fiorentina |
| 17 | Gary Medel | CHI | D | 1.72 | 71 | 03-08-87 | Santiago | Internazionale |
| 18 | Gonzalo Jara | CHI | D | 1.78 | 77 | 29-08-85 | Santiago | Mainz |
| 19 | Felipe Gutiérrez | CHI | M | 1.70 | 64 | 08-10-90 | Valparaíso | FC Twente |
| 20 | Charles Aránguiz | CHI | M | 1.72 | 67 | 17-04-89 | Santiago | Internacional |
| 21 | Marcelo Díaz | CHI | M | 1.66 | 64 | 30-12-86 | Santiago | Hamburg |
| 22 | Ángelo Henríquez | CHI | F | 1.80 | 77 | 13-04-94 | Santiago | Dinamo Zagreb (On Loan) |
| 23 | Johnny Herrera | CHI | G | 1.83 | 78 | 09-05-81 | Angol | Universidad de Chile |